Posted by Kenneth Burch On August - 3 - 2014 Comments Off on α−RuCl3: A spin-orbit assisted Mott insulator on a honeycomb lattice

We examine the role of spin-orbit coupling in the electronic structure of α−RuCl3, in which Ru ions in 4d5 configuration form a honeycomb lattice. Our x-ray absorption spectroscopy measurements at the Ru L edges exhibit distinct spectral features associated with the presence of substantial spin-orbit coupling, as well as an anomalously large branching ratio. Furthermore the measured optical spectra can be described very well with first-principles electronic structure calculations obtained by taking into account both spin-orbit coupling and electron correlations. We propose that  α−RuCl3 is a spin-orbit assisted Mott insulator, and that the bond-dependent Kitaev interaction may be important for understanding magnetism of this compound.

 

PHYSICAL REVIEW B 90, 041112(R) (2014)Adobe_PDF_icon

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